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Why is There No Standardized Furnace Designed for Copper Smelting?

Copper smelting furnaces come in various types, including flash furnaces, Australian furnaces, SKS furnaces, silver furnaces, and Noranda furnaces. Many people might wonder after reading this: since all these furnace types can complete matte smelting, why isn’t there a single furnace type suitable for all copper smelters? The reason is simple: copper smelting isn’t a “furnace selection competition,” but rather a “system matching battle.” Flash furnaces emphasize large-scale continuous operation and stable concentrate; top-blown furnaces emphasize strong stirring and adaptability to complex materials; bottom-blown furnaces emphasize the internal reaction of the molten pool and flue gas conditions; and side-blown furnaces emphasize continuous organization and control of the side reaction zone. There is no absolutely optimal furnace type, only what is suitable or unsuitable.

Conclusion: There is no one-size-fits-all furnace, only system compatibility.

Many people, when discussing furnace types, like to ask: Which furnace is the best? This question is actually difficult to answer. Copper smelting isn’t about choosing a single “one-size-fits-all” piece of equipment, but rather selecting a complete process system. The quality of a furnace depends not only on the furnace itself, but also on: the raw material conditions; the stability of the concentrate grade; the suitability of sulfur, iron, and silicon content; the level of impurities; the proportion of return material and dust; the compatibility of the flue gas acid production system; how the slag is handled; whether it’s connected to a converter or continuous blowing; the affordability of investment and operating costs; and the level of on-site operation and maintenance. Therefore, different furnace types are not simply a matter of advanced versus outdated. More accurately, they solve different problems.

Flash Furnace: Suitable for stable concentrates and large-scale continuous production.

The core characteristic of flash smelting is that the ore reacts in the air. Dried fine-grained copper concentrate and oxygen-enriched air enter the reaction tower, where oxidation, exothermic reaction, melting, and preliminary matte formation are rapidly completed in a suspended state. The advantages of flash furnaces are obvious: fast reaction speed; high thermal efficiency; high degree of continuous operation; better SO₂ conditions in the flue gas; and suitability for large-scale production. This is why the Outokumpu flash furnace has become one of the important mainstream furnace types in modern copper smelting.

Flash Furnace
Flash Furnace

However, flash furnaces also have their own prerequisites: they rely heavily on dry ore, stable particle size, stable batching, and good injection organization. In other words, they are well-suited for processing concentrates with stable conditions and thorough preparation, but they also have relatively high requirements for raw material fluctuations, complex material proportions, and the preparation system.

So, what are flash furnaces suitable for? Flash furnaces are suitable for large-scale, efficient, and continuous production under stable concentrate conditions.

Top-blown furnaces: Suitable for strong stirring and handling complex materials

Typical examples of top-blown furnaces are the Åbo furnace and the ISA furnace. Its core is the top-immersion lance. The lance is inserted into the molten pool from the top of the furnace, injecting oxygen-enriched air, fuel, etc., into the molten pool.

The keyword for top-blown furnaces is: strong stirring. Once the molten pool is agitated, the contact between gas, liquid, and solid is significantly enhanced, leading to increased heat and mass transfer. Materials entering the molten pool do not float quietly on the surface and react slowly; instead, they are quickly drawn into the melt to participate in the reaction. Therefore, top-blown furnaces are highly adaptable to complex copper-containing materials, return materials, fumes, and cold materials.

 

However, top-blown furnaces are not a “one-size-fits-all” solution. Attention must be paid to lance lifespan, lance position, molten pool splashing, slag entrainment, and subsequent settling and depletion pressure. Strong agitation is an advantage, but it also results in more thorough mixing of slag and matte, requiring careful handling of copper content and separation issues in the slag.

So, what are top-blown furnaces suitable for? Top-blown furnaces are suitable for systems requiring strong agitation, high adaptability to complex materials, and a high proportion of return materials and fumes. Their advantage is not being the “cleanest,” but rather their ability to “quickly draw complex materials into the reaction.”

Bottom-blown furnace: Suitable for organizing reactions from within the molten pool

A representative bottom-blown furnace is the SKS furnace, also known as the Shuikoushan oxygen bottom-blown smelting furnace. Its core characteristic is that oxygen enters the molten pool from the bottom. More specifically, oxygen enters the copper matte layer from the bottom, forming rising bubbles, molten circulation, and intense reactions within the molten pool.

The advantages of a bottom-blown furnace are: sufficient gas-liquid contact; deep reaction within the molten pool; better oxygen utilization conditions; relatively small flue gas volume; and better SO₂ flue gas conditions. These characteristics are beneficial for subsequent acid production and environmental control.

However, the most challenging aspect of a bottom-blown furnace is also clear: the bottom gas supply system. Because oxygen enters from the bottom, the oxygen lance, tuyeres, bottom refractory materials, sealing, and maintenance are all crucial. Problems with the bottom oxygen supply system are difficult to resolve. Simultaneously, due to the strong agitation during bottom blowing, attention must still be paid to slag copper content, Fe₃O₄, slag viscosity, and slag-matte separation.

So, what is a bottom-blown furnace suitable for? Bottom-blown furnaces are suitable for systems emphasizing internal molten pool reactions, flue gas acid production conditions, and environmental control, but they require high stability in the gas supply from the furnace bottom. Their advantage lies in deepening the reaction from within the molten pool; their challenge also lies at the furnace bottom.

Side-blown furnaces: Suitable for continuous operation and control of the side reaction zone

Representative side-blown furnaces include the Baiyin furnace, Noranda furnace, and Vanyukov furnace. Their core characteristic is that gas enters the molten pool from the side of the furnace body. Side blowing is neither from top to bottom nor bottom to top, but rather from the side tuyeres, driving the melt to form a lateral flow and reaction zone.

The advantages of side-blown furnaces are: relatively intuitive furnace structure; flexible reaction zone layout; suitability for continuous operation; and strong material adaptability. For example, the Baiyin furnace emphasizes the separation of the smelting and settling zones, with a strong reaction at the front and clarification and separation at the back. The Noranda furnace is a horizontal furnace body, organizing the reaction and settling along its length. The Vanyukov furnace emphasizes slag-blown smelting, relying on side-blown oxygen-enriched gas to enhance slag agitation and reaction.

However, side-blown furnaces also present typical challenges: erosion in the tuyeres area; slag line scouring; furnace lining life; localized overheating; copper content control in the slag; and internal flow organization.

So, what are side-blown furnaces suitable for? Side-blown furnaces are suitable for systems with continuous side-blown reactions, flexible process organization, and the ability to accept and manage tuyeres and furnace lining maintenance pressures. The advantages and disadvantages of side-blown furnaces actually stem from the same source: the strong molten pool disturbance caused by lateral air supply.

Choosing a furnace type shouldn’t be based solely on the furnace itself.

Often, a plant’s choice of furnace type isn’t based on just the furnace itself, but on the entire production line. For example: Is there a stable dry ore system at the front end? Is the raw material complex? Is the return material ratio high? Can the flue gas sulfuric acid production system match? Is the downstream a conventional converter or continuous blowing? Does the slag have a settling electric furnace or a slag depletion system? What are the local oxygen, electricity, and fuel costs? How stringent are the environmental protection requirements? Is there sufficient operational and maintenance capability on site? These factors combined determine whether a furnace type is truly suitable for a particular plant. Therefore, you’ll see: some plants are suited to flash furnaces; some to top-blown furnaces; some to bottom-blown furnaces; and some to side-blown furnaces. It’s not that everyone’s judgment is different, but rather that each smelter faces different challenges.

Furnace Selection: Essentially System Matching

Copper smelting is not a victory for a single piece of equipment, but a balance of the entire system. The furnace type is only one component. What truly needs matching are: the raw material system; the smelting system; the blowing system; the slag treatment system; the flue gas acid production system; the environmental protection system; the energy system; and the operation and management system. Looking only at the furnace itself easily leads to one-sided judgments. For example, a certain furnace type might have a strong reaction, but if the subsequent slag depletion cannot keep up, the copper content in the slag may be high. A certain furnace type might have excellent flue gas conditions, but if oxygen costs are too high, its economics may not be suitable. A certain furnace type can handle complex feedstocks, but if maintenance is difficult and on-site management cannot keep up, problems will arise. A certain furnace type has high single-furnace capacity, but if the front-end feed preparation system is unstable, it is difficult to operate stably for a long time. Therefore, furnace selection is not simply “which is the best,” but rather: which is the most suitable for the entire system.

  • Flash Furnace: Large and precise. Suitable for stable concentrate production, large-scale, efficient, and continuous production.
  • Top-blown Furnace: Flexible and powerful. Suitable for strong stirring, complex materials, return materials, and fume control.
  • Bottom-blown furnace: Deep and stable. Suitable for organizing reactions from within the molten pool, with better flue gas conditions.
  • Side-blown furnace: Wide and flexible. Suitable for continuous processing and control of the side reaction zone.

Ultimately, furnace selection must return to raw materials, scale, environmental protection, investment, and process configuration.

In conclusion,

Copper smelting cannot rely on only one type of furnace. This is not because the technology is immature, but because copper smelting faces different raw materials, processes, and on-site conditions. Flash furnaces have their advantages; top-blown furnaces have their applicable scenarios; bottom-blown furnaces have their characteristics; and side-blown furnaces also have their place. It’s not about which furnace type is best, but rather, under a series of comprehensive conditions such as specific raw materials and scale, which furnace type is most suitable!

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    Magnesium Chromium Refractory Bricks for Outokumpu Flash Smelting Furnace

    As environmental protection becomes increasingly stringent, the copper metallurgical industry is facing severe challenges. Today, there are two main copper metallurgical methods: the fire method and the wet method. Among them, the fire method plays a major role, and the lining is mainly made of alkaline refractory bricks.

    There are many types of pyrometallurgical furnaces. At present, the main pyrometallurgical copper smelting equipment in the world includes flash furnaces, reverberatory furnaces, blast furnaces, Noranda furnaces, and ISA furnaces (Osmet furnaces). There are more than ten kinds of smelting equipment such as Vanukov furnaces, Mitsubishi furnaces, Tenient furnaces, electric furnaces, silver furnaces, and so on. Most processes have problems such as low production capacity, high cost, high energy consumption, and serious pollution. Seriously restricting the development of the copper metallurgical industry.

    Outokumpu flash smelting furnace
    Outokumpu flash smelting furnace

    Legend: Outokumpu flash smelting furnace

    Outokumpu Flash Smelting Furnace

    Since the advent of Outokumpu in Finland in 1949, flash smelting has gradually replaced the reverberatory furnace and blast furnace through continuous improvement, improvement, and development. Today it has become a competitive smelting technology used in today’s copper metallurgy and is generally considered the standard clean copper smelting process.

    Currently, more than 50% of global blister copper production is produced using this technology. Due to the mature flash smelting process, it has a high degree of automation, large production capacity, low energy consumption, and good environmental protection. At present, most of the newly built or renovated and expanded copper smelting enterprises in the world adopt the flash smelting process.

    Flash Furnace Structure

    Outokumpu flash smelting uses oxygen-rich air or hot air at 723~1273K as the oxidizing gas. A down-spray concentrate nozzle is installed at the top of the reaction tower. The dry concentrate and flux are sprayed into the reaction tower at high speed with oxygen-rich air or hot air and are suspended in the tower. During the downward movement of the material, an oxidation reaction occurs with the oxygen in the airflow, releasing a large amount of heat. The temperature in the reaction tower is maintained above 1673K. The material reacts rapidly (2~3s) at high temperatures, and the resulting melt settles into the sedimentation tank. Complete the matte-making and slag-making reactions, and carry out clarification and separation.

    Flash Furnace Structure
    Flash Furnace Structure

    Refractory Materials for Outokumpu Flash Smelting Furnace

    Outokumpu flash smelting furnace consists of a reaction tower, sedimentation tank, and rising flue. The operating temperature in the tower is 1400~1500℃. Its work is subject to high temperatures, chemical erosion, and charge erosion, and is easily damaged. Generally, alkaline refractory bricks are used.

    The top of the tower is suspended and built with fired magnesia-chromium hanging bricks, with a thickness of about 400mm. The lining around the spray nozzle and burner can be integrally rammed with magnesia-chromium refractory ramming material with a Cr2O3 content of 20%. First, install the finned cooling water pipe on the furnace shell. Lay a 20mm thick insulation board or refractory fiber felt, and then pound the magnesia-chromium refractory ramming material layer. Finally, the working layer is built with cast magnesia chromium bricks. The working layer of the tower wall 1m close to the top of the tower is allowed to be built with fired magnesia chrome bricks. The materials and structure used on the top of the sedimentation tank are the same as those on the top of the tower.

    Magnesia Chrome Bricks for Furnaces
    Magnesia Chrome Bricks for Furnaces

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      Water-cooled copper sleeves are installed in the slag line area of the pool wall to protect the lining body and are all built with fused magnesia-chromium bricks, while the remaining pool walls are built with fired magnesia-chromium bricks. The total thickness of the anti-arch furnace bottom of the sedimentation tank is about 1800mm. First, 20mm thick asbestos boards or insulation boards are laid against the furnace shell, and 3 layers of clay insulation bricks and 1 layer of clay bricks are laid vertically. Then pound a layer of magnesia-chromium refractory ramming material about 100mm thick. Then use fired magnesia-chromium refractory bricks to build the working layer. The rising flue is on the other side of the sedimentation tank and consists of side walls, sloping end walls, sloping tops, and flat tops. It is mainly built with ordinary fired magnesia chromium bricks.

      The lining at the lower part of the inclined end wall is easily corroded, and water-cooled copper sleeves need to be buried to increase the service life. The lining body where the sedimentation tank vault meets the reaction tower and rising flue. Steel beams are used to bear the load and water-cooled copper sleeves with fins are installed, and the working layer is integrally poured with magnesia-chromium refractory castables. Its service life is much longer than that of bricks.

      Under normal operating conditions, the service life of the refractory brick lining of a flash smelting furnace is generally 3 to 10 years. During this period, 1 to 3 medium and minor repairs are required.

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        Copper Smelting Flash Furnace Refractory

        Flash smelting is one of the most advanced copper ore smelting technique. During flash smelting, dry sulfurized fine ore powder, flux, oxygen or oxygen rich air or preheated air are injected into high temperature reaction tower hearth, the ore powder quickly realizes desulfurization, smelting, slag forming and so on. The molten metal enters into sediment bath for further slag making, and the concentrated metal can separate with slag. Flashing smelting furnace is self heating equipment, the heat is generated from sulfur oxidization in concentrate ore. This copper smelting technique combines roasting smelting and some blowing smelting together, has very high smelting intensity.

        The reaction in flash furnace features intense and fast reaction speed, large thermal release intensity and complex furnace atmosphere, so the requirement on furnace lining refracotries is very high. Flash furnaces can be divided into Outokumpu flash furnace and Inco flash furnace. They are both composed of cylindrical reaction tower, sediment bath and cylindrical flue.

        Reaction tower

        Reaction tower is the most important part of flash furnace, air flow containing concentrate ore powder is injected into tower from the top, the chemical reaction of ore powder is carried out in a transient and melts into molten flow, which enters into sediment bath with high speed. Thus, tower lining would suffer severe scouring, erosion and abrasion caused by air current and high temperature high speed molten metal. The inner lining of reaction tower usually adopts magnesia chrome bricks, the steel shell of reaction tower are cooled by spraying cold water. At upper part of reaction tower, temperature is about 900~1100℃, oxygen partial pressure is high, so Fe3O4 protection layer is formed at tower wall, so direct bonded magnesia chrome bricks can be used here. At middle and lower part of reaction tower, the temperature is relatively high, about 1350~1550℃, and this part should endure the scouring, erosion and abrasion of molten metal. So fused cast magnesia chrome bricks are used as lining bricks, and water cooling jacket is installed at this part. Tower top are built by sintered magnesia chrome bricks.

        Sediment bath

        Sediment bath is rectangular molten bath, with 2.5~5m height, 3~10m length. The function of sediment bath is to further finish slag making reaction and separate molten metal. The working environment of sediment bath refractory is also very harsh, the end wall and side wall of sediment bath also suffers the scouring and erosion of high speed high temperature air current and molten metal. Especially slag line zone furnace wall, which would be scoured by continuously  waving molten metal, and is the most quickly damaged part. So slag line magnesia chrome refractories should have good sulfur permeation resistance and slag erosion resistance. Sediment bath bottom should not only bear load but also endure high temperature and chemical corrosion, so rebounded magnesia chrome bricks can be used here.

        Smoke flue

        Smoke flue mainly suffers high temperature smoke current (containing molten slag and dust) scouring and erosion, so direct bonded magnesia chrome bricks are usually used.

        Item Fused cast magnesia chrome brick Direct bonded magnesia chrome brick Fused rebonded magnesia chrome brick Synthesized magnesia chrome bricks Magnesia chrome castable.
        MgO % ≥ 54 70 66 65 45
        Cr2O3 % ≥ 20 12 16 16 20
        SiO2 % < 2.9 1.3 2.0 1.2 4.5
        Refractoriness under load ℃ >1700 >1700 >1700 >1700 >1650
        Apparent porosity % <13 <16 <15 <15 /
        Crushing strength Mpa≥ 80 55 66 55 25
        Bulk density g/cm3 > 3.35 3.10 3.3 3.25 2.85
        Application Sediment bath slag line Sediment bath crown, ascending flue top Sediment bath side wall, reaction tower top, triangle zone, ascending flue side wall Reaction tower wall H shape beam water cooling  component surrounding

        For some parts, where has complicated structure or difficult for the masonry of firebricks, high quality magnesia chrome castable is usually used.

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          Copper Smelting Reverberator Refractories

          Copper Smelting Reverberator Description

          Copper concentrate ore smelting reverberator is rectangular, chamber type flame furnace, which adopts coal or heavy oil as fuel. The heat exchange of reverberator not only relies on flame reverberation, but also the radioactive heat transmission of furnace top, furnace wall and high temperature gases. The production process of reverberator is continuous, the smelting process takes place under oxidizing atmosphere and 1500~1550℃ temperature. Furnace slag is composed of iron, silicon, calcium and aluminum oxides. When the molten slag splashes on furnace wall and furnace top refractory masonry, the refractory materials will suffer corrosion and damage. The highest temperature in the reverberator is at furnace top, can reach to 1800℃. Refractory materials for this place should have high refractoriness under load temperature, good thermal shock resistance, high bulk density, small linear change rate and good slag corrosion resistance.

          Copper Smelting Reverberator Refractories

          The reverberator bottom mainly adopts sintered integral bottom, magnesia iron ramming mix are usually used as sintering layer material. Magnesia iron ramming mix are made from magnesia sand, iron oxide powder and brine.

          Magnesia Iron Ramming Mass Index

          Item Component Ratio Granularity/mm Note
          Magnesia sand MgO 78 % Coarse sand:3~6mm; Middle sand: 1~3mm; fine sand 0~1mm Should be dried ath 120℃~150℃ before using.
          CaO <3.5%
          SiO2 <5%
          H2O <0.5%
          Iron oxide FeO+Fe2O3 >95% 0.147~0.104 Melting point lower than 1400℃, dried at 120~150℃
          SiO2 <4%
          brine Density between 1.3~1.4g/ml

          The furnace wall of copper smelting reverberator are usually built by magnesia bricks, magnesia alumina bricks which have good corrosion resistance, thermal impact resistance. At some important parts such as powder coal combustor surrounding and converter slag entrance and so on, chrome magnesia bricks are used to prolong the service life. Large scale copper smelting reverberator usually adopts hanging type furnace top, made from magnesia alumina bricks. 

          Furnace top and vault are usually built by silica brick, magnesia alumina bricks, direct bonded magnesia chrome bricks, phosphate bonded magnesia chrome bricks. Furnace wall is built by sintered magnesia bricks, magnesia chrome bricks, chrome magnesia bricks, magnesia alumina bricks.

          Furnace bed is usually constructed by lightweight clay bricks, sintered magnesia bricks, magnesia ramming mix.

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            Copper Smelting Blast Furnace Refractory

            Copper Smelting Refractory

            Compared with steel smelting, nonferrous metals smelting has more complex crafts, longer process procedures and more types of smelting furnaces. The production crafts of copper smelting comprise: pre-processing, matte smelting, copper blowing smelting, pyro-metallurgical refining and electrolyte refining.

            Copper ore smelting methods can be classified into pyrometallurgy and wet metallurgy. Compared with wet metallurgy, pyrometallurgy has lower energy consumption, better adaptation to mineral grades and larger smelting scale, so pyro-metallurgy smelted copper accounts for 90% of all copper yield. Among copper pyrometallurgy smelting crafts, flash smelting and bath smelting are in dominant position.

            Bath smelting is a high efficient self heating smelting method, which adopts direct blasting and intense bath agitation to swiftly realize the main chemical reactions between gas, liquid and solid phases. It is suitable for the smelting, sulfuring, oxidizing, reducing, blowing smelting and fuming of nonferrous metals materials. Flash smelting is the method that feeds dry and concentrate sulfide ore, flux, oxygen or oxygen rich air, or preheated air into high temperature furnace, raw material are quickly oxidized and melted at suspension state. The pyrometallurgy of copper including two steps: copper sulfide concentrate ore making matte smelting and matte blowing smelting.

            Matte Smelting Furnace

            Matte is half done copper frit which are smelted by adding silica, lime and other flux. Copper content of matte varies based on the types of smelting furnace, usually between 30%~50%. Matte smelting furnaces can be classified into blast furnace, reverberator, flash furnace and so on. Flash furnace is in the dominant position, the second is reverberator, others are isa furnace, Noranda reactor and so on.

            Copper Blast Furnace

            The method of making matte by copper concentrate ore in inclosed blast furnace are widely used in some countries. Copper blast furnace are composed of furnace top, furnace bosh, internal crucible, furnace hearth, tuyere and so on. During smelting, concentrate ore is added into furnace through hopper, the added ore makes the furnace a closed environment. Concentrate ore, coke, flux and other solid material are loaded from furnace top, high pressure air are blew into furnace from lower part of furnace bosh tuyere equipment. The up moving hot air will fully contact with down moving materials and make them melted, oxidized or reduced. Furnace slag and matte will separate with each other when entering into fore crucible through throat. Molten slag mainly comprises SiO2-FeO-CaO series material, the highest temperature of tuyere upper part smelting zone is 1350℃.

            Copper Blast Furnace Refractory

            Furnace top cover is consisted of  cover board and water jacket, lateral side lining is made of chamotte bricks and asbestos board, covered by steel board. Furnace are consisted of water jackets, throat hole and furnace bottom are built by magnesia bricks.

            Copper blast furnace upper part usually adopts clay bricks, chrome bricks. Tuyere and upper oblique furnace wall is built by clay bricks. The working lining of copper blast furnace is constructed by magnesia chrome bricks or chrome bricks.

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