Refractory Configuration and Optimization for a 5000t/d Clinker Line (2)

Refractory materials are developing towards environmental friendliness, strong adaptability, and long service life. Rongsheng Refractory Materials Factory supplies refractory materials for kilns used in 5,000 t/d clinker production lines. Rongsheng Refractory Materials Manufacturer leverages its innovative capabilities in refractory castables while focusing on customer needs, aiming to provide high-quality, long-life refractory lining materials for high-temperature industrial furnaces. Contact Rongsheng for free solutions.

Refractory Lining Configuration for a 5,000 t/d Cement Clinker Production Line

This article focuses on the refractory configuration for a 5,000 t/d cement clinker production line. The cement firing system involves a complex chemical process from raw meal to clinker, going through stages such as preheating in the preheater, decomposition in the calciner, high-temperature calcination, and cooling. The refractory materials used in each stage must be adapted to this process.

(3) Kiln Head Hood

The kiln head hood connects the rotary kiln to the cooler and serves as the inlet for kiln air and tertiary air. Air pressure is extremely unstable, making positive pressure a common feature of the entire kiln system. Gas temperatures range from 800-1300°C, with significant temperature fluctuations. Furthermore, the impact of clinker particles is intense, making the top and inlet areas susceptible to damage. Therefore, thermal shock resistance and wear resistance should be considered when selecting materials.

  1. High-Alumina High-Strength Wear-Resistant Castable

Amount: 180 tons

Technical Performance:

Application Location: Round top

  1. Calcium Silicate Board

Amount: 7.2 tons

Technical Performance: See above

Application Location: All refractory linings

(4) Burner

Because the burner is located in the high-temperature gas between the kiln mouth and the cooler, and the pulverized coal burns near the burner head, it is significantly affected by the high-temperature radiation and reducing atmosphere. The chemical composition of coal significantly influences combustion, making the burner head plate susceptible to damage. The refractory material used in this area requires high refractoriness and wear resistance, as well as enhanced thermal shock stability and spalling resistance.

RS Mullite Castable Manufacturer
RS Mullite Castable Manufacturer

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    1. Mullite Castable

    Quantity: 5 tons

    Technical Performance:

     

    Application Area: Burner head hood where it enters the kiln

    (5) Rotary Kiln

    As a rotating drum that calcines raw materials into clinker at high temperatures, the lifespan of its refractory materials often determines the production cycle, making it a key and challenging aspect of refractory material management in cement plants. After preheating and approximately 90% decomposition, the raw material enters the kiln from the kiln outlet, where its temperature gradually rises to over 1450°C, completing the calcination process and entering the cooler. A 74-meter rotary kiln can be broadly divided into five thermal stages. Because the refractory materials within the rotary kiln must be fixed to the continuously rotating drum, the strength of the refractory bricks must not fall below a certain threshold due to the following factors:

    1. There is a certain degree of slippage or sliding tendency between the refractory bricks and the shell, generating friction. The refractory bricks must possess a certain strength to resist damage from this friction.
    2. A rotary kiln is not an absolutely rigid structure when viewed axially. Because the rotary kiln drum has a certain curvature between its support points, it experiences periodic bending in sync with its rotation during operation. Because the three-roller rotary kiln utilizes a statically indeterminate structure, the different expansion rates of each roller group due to temperature differences can cause deviations in the kiln shell’s coaxiality, generating significant additional loads. Furthermore, the 4% inclination of the kiln shell also generates downward stress during rotation.
    3. The shell is not a perfect circle in the radial direction, but rather an elliptical shape. Deformation is greatest at the wheel belts, and this deformation places additional pressure on the refractory bricks. Due to the kiln’s own weight and rotation, the kiln undergoes periodic elliptical deformation, synchronized with the rotation, placing alternating loads on the refractory bricks. When this deformation or elliptical deformation reaches a certain value, it can exceed the internal stresses in the refractory bricks, causing premature failure. Therefore, refractory materials with insufficient strength must be used in rotary kilns; they must meet basic strength requirements.
    4. In addition to the aforementioned mechanical stresses, the refractory materials within the kiln are also subject to the effects of high-temperature gases and liquid clinker. It can be roughly divided into five or six working zones, which require different refractory materials for laying.

    Refractory Configuration for a 5,000-ton Rotary Kiln:

    1. Mullite Castable

    Usage: 15 tons

    Technical Performance: See above (RT-70MC)

    Applicable Area: 0-0.6 m

    1. High-Abrasion-Resistant Bricks

    Usage: 8 tons

    Technical Performance:

    Applicable Area: 0.6-1.6 m

    RS Direct Bonded Magnesia Chrome Bricks
    RS Direct Bonded Magnesia Chrome Bricks

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      1. Direct-Bonded Magnesia-Chrome Bricks

      Usage: 340 tons

      Technical Performance:

      Applicable Area: 1.6-25 m/35-45 m

      Spinel Refractory Bricks
      Spinel Refractory Bricks

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        1. Spinel Bricks

        Usage: 99 tons

        Applicable Area: 25-35 m

        1. Anti-Spalling Bricks

        Usage: 242 tons

        Applicable Area: 45-73.2 m

        1. High-Alumina Castables

        Usage: 8.5 tons

        Technical Performance: See above

        Applicable Area: 73.2-74 m

        (6) Cooler

        The cooler uses air to cool the hot clinker leaving the kiln from 1400°C to below 80°C. Due to the large temperature difference between the front and rear sections, the most vulnerable parts are concentrated in the front wall and the lower wall. Furthermore, the overhanging beams at the interface with the kiln head are also susceptible to premature damage due to the erosion of high-temperature gases.

        Grate coolers are stationary relative to the refractory shell, so insulation materials with low strength but low thermal conductivity can be used on the outer layer. The cooler’s inner surface must withstand thermal erosion and high-temperature abrasion caused by contact with high-temperature clinker at 300-1450°C, so the selected refractory materials must have strong wear resistance. Furthermore, the first stage cooler must also withstand high thermal loads.

        Because the grate cooler has large vertical walls, the use of special anchoring refractory bricks is crucial when constructing the refractory brickwork to strengthen the connection between the bricks and the shell to prevent collapse of the vertical walls.

        Currently, the most commonly used refractory castables are:

        1. High-strength alkali-resistant castable

        Usage: 20 tons

        Technical properties: See above (RT-13NL)

        Application: Section 3 and top

        1. High-alumina castable

        Usage: 106 tons

        Technical properties: See above (RT-16)

        Application: Section 2 and 3 side walls and parapet

        1. High-heat high-alumina castable

        Usage: 183 tons

        Application: Cooler front wall and Section 1 parapet

         

        (To be continued…)

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          Corundum Castable that is Resistant to High Temperatures and Slag Erosion

          Corundum castable is a high-grade castable in a series of unshaped refractory materials. It has a stable crystal structure has more stable performance in high-temperature sintering processes, and is suitable for use in high-temperature areas lined with various kilns. Corundum castable that is resistant to high temperatures and slag erosion. Refractory castables made of this material can better reflect its fire resistance and wear resistance at high temperatures. Its thermal shock resistance can also achieve better performance at high temperatures, and its performance is reliable and reliable during high-temperature operation of the kiln.

          Corundum Castable
          RS High-Grade Corundum Castable

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            High-Grade Corundum Castable

            Corundum castable is used in high-temperature parts of industrial kilns between 1400℃ and 1650℃. It is produced using bauxite clinker and corundum with an aluminum content of more than 90% as aggregate, using micro-powder technology and pure calcium aluminate cement. This kind of corundum refractory castable has high strength, high volume density, and strong high-temperature stability. Used in high-temperature parts of industrial kiln linings, it has strong resistance to slag erosion, wear resistance, and high-temperature gas erosion resistance.

            Performance Characteristics of Corundum Castables

            Corundum castables have high-energy effects of high temperature resistance and corrosion resistance, and can still maintain stable performance under long-term use. It can be combined with silicon carbide, mullite, andalusite, sillimanite, etc. to make composite refractory castables. It can be used in high-temperature furnace lining parts in different atmospheres.

            The high-temperature main crystal phase of corundum castable is corundum refractory castable. It is a refractory castable prepared with special high-alumina bauxite clinker or fused brown corundum as aggregate, adding refractory powder, pure calcium aluminate cement binder, silica powder, and admixtures. Usually, the pouring method is used for construction. It can be cast into a complete lining, or prefabricated blocks of castable materials customized by the manufacturer can be spliced on-site for use.

            Corundum Castable Refracotry for the C F B Boiler
            Corundum Castable Refractory of Slag Corrosion Resistance

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              Product Features of Corundum Castables

              • (1) High compressive strength and strong lining stability at high temperatures.
              • (2) The volume density is high, and the overall lining has strong resistance to slag erosion and permeability.
              • (3) Strong resistance to erosion by solid particles, dust, and high-temperature gases.
              • (4) Low mechanical wear resistance.
              • (5) Not affected by reducing gases such as H2 and CO.

              Corundum Castable Product Uses

              The use temperature of corundum castable is 1600-1700℃, and it is mainly used as lining material for various high-temperature kilns and high-temperature structures. Such as the outer lining of the impregnation tube of the molten steel vacuum degassing device, the lining of the spray metallurgy, and the argon-blowing integral spray gun. The lining body of the electric furnace top triangular area and the LF furnace cover. High-temperature wear-resistant lining for catalytic cracking reactors in the petrochemical industry. High-temperature wear-resistant lining for circulating fluidized beds and power plant boilers.

              How to Improve the High-Temperature Slag Corrosion Resistance of Corundum Castables?

              The development trend of dense refractory castables requires the calcium aluminate cement content to be reduced as much as possible while maintaining good green strength and high-temperature mechanical properties. The key technology is to increase the packing density between particles. The above purpose can be effectively achieved by adding micron powder, submicron powder, or even nano-alumina powder. The reasons are:

              • 1) Reduce the CaO content in the castable and reduce the low melting phase generated at high temperatures. It can significantly improve the high-temperature mechanical properties of castables.
              • 2) Promote sintering at medium temperature and increase the medium temperature strength of castables.
              • 3) Reduce the total amount of water added and increase the density of the castable.
              Corundum Refractory Castable
              Corundum Castable Refractory Lining Materials

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                In terms of comprehensive cost performance, the role of alumina micropowder cannot be ignored. Its particle morphology, size, particle size distribution and specific surface area will have a great impact on the performance of the castable. In particular, the particle size distribution plays an important role in filling the pores between aggregates and increasing the packing density. Research has found that using composite micropowders with different particle size distributions can significantly increase the packing density. Reducing water consumption is beneficial to mechanical properties such as high-temperature flexural resistance and post-thermal shock strength. Li Wenping studied the influence of alumina powder particle size on the properties of castables. It was found that as the particle size of the micropowder decreases, the flowability and setting time of the castables both show an increasing trend.

                More importantly, alumina micro-powder can promote the formation reaction of the CA6 phase of calcium aluminate cement at high temperatures, thereby significantly improving the high-temperature properties of castables. Pinto et al. found that the particle size of alumina powder decreased. It can nearly double the flexural strength of castables containing 1% (mass fraction) CAC cement and promote the formation of the CA6 phase. Auvray et al. discovered the optimization of alumina micro-powder and the in-situ generation of CA6. Ceramic bonding can be formed in the castable, which significantly improves the high-temperature elastic modulus of the castable. Specifically,

                • 1) As the alumina fine powder content increases and the corundum fine powder content decreases, the normal temperature performance and high-temperature performance of the castable samples after heat treatment at different temperatures are improved to varying degrees. After being treated at 1600°C, the normal temperature flexural strength, normal temperature elastic modulus, and elastic modulus at 1400°C can be increased by 53.9%, 47.9%, and 40.4% respectively.
                • 2) Adding too much micro powder is detrimental to the thermal shock stability of the castable. The more the amount of alumina powder is added, the residual flexural strength retention rate of the sample after thermal shock decreases with the increase in the amount of alumina powder. After three water-cooling thermal shocks, the residual flexural strength retention rate of the material decreased from 18.45% to 11.97%.
                • 3) As the content of aluminum oxide powder increases, the slag erosion resistance of the castable gradually increases, and the thickness of the permeable layer decreases from 2.9mm to 2.1mm. The higher content of micro-powder will make the pore diameter of the castable smaller, promote the interpenetration and bonding of plate-like CA6 in the original layer, and make the matrix bonding closer. It is beneficial to improve the slag resistance performance of castables.

                To purchase high-quality corundum castable refractory lining materials, please contact us.

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